Pyrolysis gasoline from Ethylene unit is sent to a recovery unit to recover C7 minus components. These are recovered in two columns under vacuum. Maximum temperature is at the bottom of the second column which is ~ 145 deg C. Unrecovered stuff is sent to Utilities as liquid fuel.
Anti-oxidant injection is done in the Ethylene unit as Pygas contains precursors such as dienes which can lead to polymerisation.
Recovery unit was operating steady, without any problems, for 8 months. Now for some reason the frequency of choking of the strainer of bottoms pump of the last column has increased dramatically. Also, we are experiencing frequent choking of burner guns. Material found is coffee coloured granules which become powder when subjected to pressure.
Trying to understand root cause. Not much has changed in terms of operating conditions. Very few component analyses are done in the whole system and not much information is available.
Hope to get some inputs based on experience in similar units.